ASTM A959 - 19

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Designation: A959 −19
Standard Guide for
Specifying Harmonized Standard Grade Compositions for
Wrought Stainless Steels
1
This standard is issued under the fixed designation A959; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This guide provides a guide to ASTM Subcommittees
A01.06, A01.10, A01.17, A01.22, and A01.28 for specifying
chemical composition limits of wrought stainless steels. It is
intended that these recommended grade composition limits be
suitable for adoption by other standardization bodies that
prepare standards for stainless steel products.
1.2 Included in this guide are the recommendations for
determining the number of significant figures for specifying
chemical composition from Test Methods, Practices, and Ter-
minology A751.
1.3 All stainless steel UNS numbers and the stainless steel
grades in all standards overseen by the aforementioned ASTM
subcommittees have been included, except those grades appli-
cable to restricted special end uses and alloys containing less
than 10.5 % minimum chromium.
1.4 Not addressed are minor composition modifications
which a specific product subcommittee may find necessary to
accommodate effects of normal processing or to enhance
fabricability by the producer or user, or both.
1.5 Also not generally addressed (except when established
by ASTM product subcommittees) is a complete rationalization
of all limits, especially when such would conflict with long-
standing practices and is not justified by special technical
effect.
1.6 Excluded from this guide are cast material and welding
filler metal.
1.7 This international standard was developed in accor-
dance with internationally recognized principles on standard-
ization established in the Decision on Principles for the
Development of International Standards, Guides and Recom-
mendations issued by the World Trade Organization Technical
Barriers to Trade (TBT) Committee.
2. Referenced Documents
2.1 ASTM Standards:
2
A751 Test Methods, Practices, and Terminology for Chemi-
cal Analysis of Steel Products
E527 Practice for Numbering Metals and Alloys in the
Unified Numbering System (UNS)
2.2 SAE Standards:
3
J 1086 Recommended Practice for Numbering Metals and
Alloys
HS-1086 Metals and Alloys in the Unified Numbering Sys-
tem
3. Terminology
3.1 Definitions of Terms Specific to This Standard:
3.1.1 austenitic grade, n—metallurgical term meaning that
the material is usually predominantly face-centered cubic in
structure and hardenable only by cold working.
3.1.2 austenitic-ferritic (duplex) grade, n—metallurgical
term meaning that the material is a mixture of austenitic and
ferritic structures, with at least one-fourth of the lesser phase,
and hardenable only by cold working.
3.1.3 ferritic grade, n—metallurgical term meaning that the
material is body-centered cubic in structure (with little, if any,
tempered martensite) and hardenable only slightly by cold
working (responding little or only slightly to conventional heat
treatment by quenching and tempering).
3.1.4 martensitic grade, n—metallurgical term meaning that
the material is capable of being produced in a distorted
body-centered cubic structure by conventional heat treating
and quenching, and that the quenched structure is capable of
conventional tempering. Martensitic grades are delivered in the
annealed (ferritic) condition or the hardened and tempered
(martensitic) condition.
3.1.5 precipitation hardening grade, n—metallurgical term
meaning that the material may be basically austenitic or
1
This guide is under the jurisdiction of ASTM Committee A01 on Steel,
Stainless Steel and Related Alloysand is the direct responsibility of Subcommittee
A01.17 on Flat-Rolled and Wrought Stainless Steel.
Current edition approved Nov. 15, 2019. Published November 2019. Originally
approved in 1996. Last previous edition approved in 2016 as A959 – 16. DOI:
10.1520/A0959-19.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website.
3
Available from Society of Automotive Engineers (SAE), 400 Commonwealth
Dr., Warrendale, PA 15096-0001, http://www.sae.org.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
1
martensitic in structure and hardenable by precipitation hard-
ening (sometimes called age hardening).
3.1.6 standard stainless steel grade, n—listed chemical
composition associated with a stainless steel grade identified
by a particular UNS number appearing in SAE publication
HS-1086, except as modified by an ASTM subcommittee
having oversight of a wrought stainless steel product where
such a modification is justified by a specific technical effect.
4. Significance and Use
4.1 It is anticipated that the ASTM Subcommittees A01.06,
A01.10, A01.17, A01.22, and A01.28 will use the standard
composition limits listed in this guide for the grades identified
by the corresponding UNS designation in the product specifi-
cation unless there is a specific technical justification for doing
otherwise. The compositions in this guide shall not be consid-
ered as chemical requirements for any particular product until
adopted by the subcommittee overseeing that product.
4.2 Assuming that uniform compositions among the many
product standards for stainless steel are desirable, the compo-
sition limits provided in this standard are to be used as guides
in determining limits for each of the elements included in the
total composition of each grade. The composition limits have
been established with the intent that each product subcommit-
tee will find it necessary to require only a minimum number of
changes to reflect specific technical effects. Section 5lists the
general guidelines followed for determining the limits for each
element; the limits established in this guide are based on these
guidelines.
4.3 Not included in this standard stainless steel grade
harmonization effort is an attempt to unify stainless steel
compositions in ASTM product standards by any means other
than recognizing current industry practices.
5. General Guidelines Used for Determining Composition
Limits
5.1 Carbon—It is recommended that limits be to only two
decimal places for levels of 0.04 % and higher because it is not
necessary to control to such precision at levels above 0.04 %.
(It should be recognized that limits such as 0.045 % maximum
may also be simply stated as 0.04 % maximum.) It is also
recommended that three decimal places be used at levels of
0.030 % and lower, unless, for example, it is clearly recognized
that 0.03 % maximum means that 0.035 % is satisfactory.
5.2 Manganese—Except for the Cr-Ni-Mn grades
(S2XXXX), it is recommended that limits of 2 % maximum
and 1 % maximum be used for the austenitic and other grades
respectively, except for the free machining grades with high
sulfur or selenium, or when necessary to promote nitrogen
solubility.
5.3 Phosphorus—It is recommended that 0.045 % maxi-
mum be applied to austenitic grades, and 0.040 % maximum to
other grades unless the sponsoring producer recommends a
lower limit for specific technical effect. Exception—some of
the Cr-Ni-Mn austenitic grades have always been produced to
0.060 % maximum.
5.4 Sulfur—It is recommended that 0.030 % maximum be
applied to all grades except the free-machining grades unless
lower limits have been required for specific technical effects.
5.5 Silicon—Past practice has been to establish 0.75 %
maximum for tubular related products such as flat rolled and
tubulars, and 1.00 % maximum for long products and forgings.
For grades produced both as long and flat-rolled products, 1 %
maximum was chosen since it will also include products
melted to lower limits. Use of lower or higher limits should be
based on specific technical effect.
5.6 Chromium—A composition spread of 2 % is recom-
mended; existing broader limits were not reduced to less than
a 3 % spread.
5.7 Nickel—It is recommended that the composition spread
not exceed 3 % unless a broader (generally higher) spread is
justified by specific technical effect.
5.8 Molybdenum—It is recommended that the composition
spread not exceed 1 %, unless a broader range is justified by
specific technical effect. Molybdenum limits having only a
maximum limit but no minimum should not be used unless
justified by specific technical effect.
5.9 Nitrogen—It is recommended that nitrogen limits having
only a maximum limit but no minimum should not be used
unless justified by specific technical effect.
5.10 Copper—It is recommended that copper limits having
only a maximum limit but no minimum should not be used
unless justified by specific technical effect.
5.11 Columbium and Tantalum—Except for special applica-
tions requiring positive identification of tantalum, it is recom-
mended that prior listings of these two elements together be
limited to listing only columbium. The words “columbium”
and “niobium” refer to the same element.
6. Harmonized Standard Grade Stainless Steel
Compositions
6.1 The harmonized composition limits are shown in Table
1, grouped by metallurgical classification, that is, austenitic,
austenitic-ferritic, and so forth. Within those groups, grades are
listed by UNS designation, in numerical order.
6.2 Unless adopted by the appropriate product subcommit-
tee in a product standard, the compositions described in this
guide shall not be used for specifying an ASTM product.
7. Keywords
7.1 austenitic stainless steels; austenitic-ferritic or ferritic-
austenitic stainless steels; duplex stainless steels; ferritic stain-
less steels; harmonized stainless steel compositions; marten-
sitic stainless steels; precipitation hardening stainless steels;
standard stainless steel grade compositions
A959 − 19
2
TABLE 1 Chemical Composition Limits, %
A
UNS
Designation
B
Type
C
Carbon Manganese Phosphorus Sulfur Silicon Chromium Nickle Molybdenum Nitrogen Copper Other Elements
Austenitic Grades
S16800 16-8-2H
D
0.05–0.10 2.00 0.045 0.030 1.00 14.5–16.5 7.5–9.5 1.50–2.00 . . . . . . . . .
S20100 201 0.15 5.5–7.5 0.060 0.030 1.00 16.0–18.0 3.5–5.5 . . . 0.25 . . . . . .
S20103 201L 0.03 5.5–7.5 0.045 0.030 1.00 16.0–18.0 3.5–5.5 . . . 0.25 . . . . . .
S20153 201LN
D
0.03 6.4–7.5 0.045 0.015 1.00 16.0–17.5 4.0–5.0 . . . 0.10–0.25 1.00 . . .
S20161 . . . 0.15 4.0–6.0 0.045 0.030 3.0–4.0 15.0–18.0 4.0–6.0 . . . 0.08–0.20 . . . . . .
S20162 . . . 0.15 4.0–8.0 0.040 0.040 2.5–4.5 16.5–21.0 6.0–10.0 0.50–2.50 0.05–0.25 . . . . . .
S20200 202 0.15 7.5–10.0 0.060 0.030 1.00 17.0–19.0 4.0–6.0 . . . 0.25 . . . . . .
S20300 XM-1
E
0.08 5.0–6.5 0.045 0.18–0.35 1.00 16.0–18.0 5.0–6.5 . . . . . . 1.75–2.2 . . .
S20400 . . . 0.030 7.0–9.0 0.045 0.030 1.00 15.0–17.0 1.50–3.00 . . . 0.15–0.30 . . . . . .
S20430 . . . 0.15 6.5–9.0 0.060 0.030 1.00 15.5–17.5 1.50–3.50 . . . 0.05–0.25 2.0–4.0 . . .
S20431 . . . 0.12 5.0–7.0 0.045 0.030 1.00 17.0–18.0 2.0–4.0 . . . 0.10–0.25 1.50–3.50 . . .
S20432 . . . 0.08 3.0–5.0 0.045 0.030 1.00 17.0–18.0 4.0–6.0 . . . 0.05–0.20 2.00–3.00 . . .
S20433 . . . 0.08 5.5–7.5 0.045 0.030 1.00 17.0–18.0 3.5–5.5 . . . 0.10–0.25 1.50–3.50 . . .
S20500 205 0.12–0.25 14.0–15.0 0.060 0.030 1.00 16.5–18.0 1.00–1.75 . . . 0.32–0.40 . . . . . .
S20910 XM-19
E
0.06 4.0–6.0 0.045 0.030 1.00 20.5–23.5 11.5–13.5 1.50–3.00 0.20–0.40 . . . Nb
H
0.10–0.30,
V 0.10–0.30
S21400 XM-31
E
0.12 14.0–16.0 0.045 0.030 0.30–1.00 17.0–18.5 1.00 . . . 0.35 min . . . . . .
S21460 XM-14
E
0.12 14.0–16.0 0.060 0.030 1.00 17.0–19.0 5.0–6.0 . . . 0.35–0.50 . . . . . .
S21500 . . . 0.06–0.15 5.5–7.0 0.045 0.030 0.2–1.0 14.0–16.0 9.0–11.0 0.80–1.20 . . . . . . Nb 0.75–1.25,
V 0.15–0.40,
B 0.003–0.009
S21600 XM-17
E
0.08 7.5–9.0 0.045 0.030 1.00 17.5–20.5 5.0–7.0 2.00–3.00 0.25–0.50 . . . . . .
S21603 XM-18
E
0.03 7.5–9.0 0.045 0.030 1.00 17.5–20.5 5.0–7.0 2.00–3.00 0.25–0.50 . . . . . .
S21640 . . . 0.08 3.5–6.5 0.060 0.030 1.00 17.5–19.5 4.0–6.5 0.50–2.00 0.08–0.30 . . . Nb 0.10–1.00
S21800 . . . 0.10 7.0–9.0 0.060 0.030 3.5–4.5 16.0–18.0 8.0–9.0 . . . 0.08–0.18 . . . . . .
S21900 XM-10
E
0.08 8.0–10.0 0.045 0.030 1.00 19.0–21.5 5.5–7.5 . . . 0.15–0.40 . . . . . .
S21904 XM-11
E
0.04 8.0–10.0 0.045 0.030 1.00 19.0–21.5 5.5–7.5 . . . 0.15–0.40 . . . . . .
S24000 XM-29
E
0.08 11.5–14.5 0.060 0.030 1.00 17.0–19.0 2.3–3.7 . . . 0.20–0.40 . . . . . .
S24100 XM-28
E
0.15 11.0–14.0 0.045 0.030 1.00 16.5–19.0 0.50–2.50 . . . 0.20–0.45 . . . . . .
S28200 . . . 0.15 17.0–19.0 0.045 0.030 1.00 17.0–19.0 . . . 0.75–1.25 0.40–0.60 0.75–1.25 . . .
S30100 301 0.15 2.00 0.045 0.030 1.00 16.0–18.0 6.0–8.0 . . . 0.10 . . . . . .
S30103 301L
D
0.030 2.00 0.045 0.030 1.00 16.0–18.0 5.0–8.0 . . . 0.20 . . . . . .
S30116 301Si 0.15 2.00 0.045 0.030 1.00–1.35 16.0–18.0 6.0–8.0 1.00 0.20 . . . . . .
S30153 301LN
D
0.030 2.00 0.045 0.030 1.00 16.0–18.0 5.0–8.0 . . . 0.07–0.20 . . . . . .
S30200 302 0.15 2.00 0.045 0.030 1.00 17.0–19.0 8.0–10.0 . . . 0.10 . . . . . .
S30215 302B 0.15 2.00 0.045 0.030 2.00–3.00 17.0–19.0 8.0–10.0 . . . 0.10 . . . . . .
S30300 303 0.15 2.00 0.20 0.15 min 1.00 17.0–19.0 8.0–10.0 . . . . . . . . . . . .
S30310 XM-15
E
0.15 2.5–4.5 0.20 0.25 min 1.00 17.0–19.0 7.0–9.0 . . . . . . . . . . . .
S30323 303Se 0.15 2.00 0.20 0.06 1.00 17.0–19.0 8.0–10.0 . . . . . . . . . Se 0.15 min
S30345 XM-2
E
0.15 2.00 0.05 0.11–0.16 1.00 17.0–19.0 8.0–10.0 0.40–0.60 . . . . . . Al 0.60–1.00
S30400 304 0.07 2.00 0.045 0.030 1.00 17.5–19.5 8.0–11.0 . . . . . . . . . . . .
S30403 304L 0.030 2.00 0.045 0.030 1.00 17.5–19.5 8.0–12.0 . . . . . . . . . . . .
S30409 304H 0.04–0.10 2.00 0.045 0.030 1.00 18.0–20.0 8.0–11.0 . . . . . . . . . . . .
S30415 . . . 0.04–0.06 0.80 0.045 0.030 1.00–2.00 18.0–19.0 9.0–10.0 . . . 0.12–0.18 . . . Ce 0.03–0.08
S30430 . . . 0.03 2.00 0.045 0.030 1.00 17.0–19.0 8.0–10.0 . . . . . . 3.0–4.0 . . .
S30432 . . . 0.07–0.13 0.50 0.045 0.030 0.30 17.0–19.0 7.5–10.5 . . . 0.05–0.12 2.5–3.5 Nb 0.20–0.60,
Al 0.003–0.030,
B 0.001–0.010
S30434 . . . 0.07–0.14 2.00 0.040 0.010 1.00 17.5–19.5 9.0–12.0 . . . . . . 2.50–3.50 Nb 0.10–0.40
G
,
Ti 0.10–0.25
G
,
B 0.001–0.004
S30435 . . . 0.08 2.00 0.045 0.030 1.00 16.0–18.0 7.0–9.0 . . . . . . 1.50–3.00 . . .
S30441 . . . 0.08 2.00 0.045 0.030 1.0–2.0 17.5–19.5 8.0–10.5 . . . 0.10 1.5–2.5 Nb 0.1–0.5,
W 0.2–0.8
S30451 304N 0.08 2.00 0.045 0.030 1.00 18.0–20.0 8.0–11.0 . . . 0.10–0.16 . . . . . .
S30452 XM-21
E
0.08 2.00 0.045 0.030 1.00 18.0–20.0 8.0–10.0 . . . 0.16–0.30 . . . . . .
A959 − 19
3
摘要:

ASTM A959-19 是 ASTM 国际标准组织发布的不锈钢牌号成分与规格协调指南,全称为“Standard Guide for Specifying Harmonized Standard Grade Compositions for Wrought Stainless Steels”(锻制不锈钢统一标准牌号成分指南)。该标准为不锈钢制造商、工程师和采购方提供了一套统一的化学成分和牌号命名规则,确保不同生产商之间的不锈钢产品在性能与成分上保持一致。ASTM A959-19 覆盖奥氏体、铁素

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